A student must know the fundamentals, such as the essence of structure and bonding in organic molecules, the nature of the basic reactive intermediates, and organic reaction mechanisms. We seek to rectify that situation with this text. For some time it has been true that if a student opens a physical organic chemistry textbook to a random page, the odds are good that he or she will see very interesting chemistry, but chemistry that does not represent an area of significant current research activity. This book is meant to capture the state of the art of physical organic chemistry in the early twenty-first century, and, within the best of our ability, to present material that will remain relevant as the field evolves in the future.
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